4.7 Article

Asymmetric Epoxidation of Fluoroolefins by Chiral Dioxirane. Fluorine Effect on Enantioselectivity

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 21, Pages 8377-8380

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo901553t

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Funding

  1. National Institutes of Health [GM59705-08]

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The asymmetric epoxidation of various fluoroolefins has been studied using chiral ketone catalyst, and Lip to 93% cc was achieved With fructose-derived ketone 1

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