Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 22, Pages 8690-8694Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo901612j
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N-(Pg-alpha-aminoxy acids) 1a-g are converted to N-(Pg-alpha-aminoxyacyl)benzotriazoles 2a-g, Which react under mild conditions with amines, alpha-amino acids/alpha-dipeptides, and alpha-aminoxy acids to give aminoxyacyl amides 3a-g, (3e + 3e'), and (3g + 3g'), aminoxy hybrid peptides 4a-h, (4a + 4a'), 6a-d, 9a-c, (9a + 9a'), and (9b + 9b'), and a-aminoxy peptides 10a,b in good yields without racemization.
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