Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 8, Pages 3211-3213Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo900113s
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A short and efficient approach to aza-quaternary pyrrolo[1,2-a]azepine 8 and aza-quaternary indolizine 23, as the crucial intermediates for syntheses of stemonamine (1a) and cephalotaxine (1b), has been developed on the basis of the key intramolecular Schmidt reaction of symmetric azidodiones 5 and 18, respectively.
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