Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 9, Pages 3579-3582Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo9001189
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- Ministry of Education, Culture, Sports, Science and Technology, Japan [18550058]
- Grants-in-Aid for Scientific Research [18550058] Funding Source: KAKEN
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3,3'-Diethyl substituents of the 2,2'-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/pi interactions and remarkably accelerate syn-anti conformational change of the 2,2'-bipyrrole components leading to helicity change in the figure eight loop of [32]octaphyrins.
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