Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 11, Pages 4375-4378Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo9007332
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Funding
- NSFC
- Chinese Academy of Sciences
- State Key Basic Research Program
- NSFC-DFG joint project [TRR61]
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Electron transfer can occur from the TTF units to the substituted quinone unit in a new TTF-quinone-TTF triad 1 containing the N,N-dialkylaniline-substituted quinone unit flanked by two TTF units, in the presence of metal ions (Pb2+, Zn2+, and Sc3+). Simultaneously, the corresponding charge transfer within the substituted quinone unit becomes weak in the presence of metal ions. Moreover, the metal ion-promoted electron transfer and the intramolecular charge transfer can be tuned by alternating UV and visible light irradiation in the presence of spiropyran.
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