Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 18, Pages 7428-7431Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801371w
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Funding
- Zhejiang Provincial Natural Science Foundation of China [R407106]
- Natural Science Foundation of China [205710631]
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Mild conditions have been developed to achieve Pd(OAc)(2)-catalyzed regioselective cross-coupling between indoles and potassium aryltrifluoroarylborates in the presence of Cu(OAc)(2) in acetic acid at room temperature. A variety of potassium aryltrifluoroborates selectively undergo the direct arylation across indoles and afford 2-aryl indoles in moderate to good yields.
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