Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 8, Pages 3262-3265Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo800168h
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Short alpha/beta-peptides, containing conformationally restricted cis-beta-aminocyclopropylcarboxylic acid units as turn-inducing elements, have been found to be efficient catalysts for inter- and intramolecular aldol reactions. The tripeptide H-(L)-Pro-triangle-(L)-Pro-OH was identified to perform especially well in homogeneous and heterogeneous aqueous solutions as well as in organic solvents.
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