Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 12, Pages 4559-4567Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo8004827
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- NIGMS NIH HHS [GM 075855] Funding Source: Medline
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Piperine, a natural product containing a conjugated diene, was reacted with polymer-supported acyl- and arylnitroso dienophiles. The reactions with arylnitroso dienophiles were also carried out in solution. The oxazine rings formed by the corresponding hetero-Diels-Alder reactions were further transformed and novel acyclic as well as heterocyclic derivatives including pyrroles and quinoxalinones were prepared.
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