Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 13, Pages 5167-5169Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo8008676
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Funding
- NIGMS NIH HHS [F31 GM081905, R01 GM046059, F31 GM081905-01, GM46059, F31GM081905, R01 GM058160, R37 GM046059, GM58160, R01 GM058160-11] Funding Source: Medline
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Pyrrole 2-carboxylic acid (L5) was found to be an effective ligand for the Cu-catalyzed monoarylation of anilines with aryl iodides and bromides. Under the reported conditions (10% CuI/20% L5/DMSO/K(3)PO(4)/80-100 degrees C/20-24 h), a variety of useful functional groups were tolerated, and moderate to good yields of the diaryl amine products were obtained.
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