Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 22, Pages 9188-9191Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo8019797
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An alkylation of aminals with organozinc reagents derived from allyl bromide, benzyl bromide, alpha-bromoacetate, and alpha-bromonitrile proceeded efficiently in the presence of TMSCl and diisopropylamine. This reaction system was applied to the synthesis of an antispasmodic: butaverine.
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