Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 9, Pages 3530-3534Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo800287s
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Trihexyl(tetradecyl)phosphonium hexafluorophosphate, a phosphonium salt ionic liquid (PSIL) is a particularly effective general reaction media for the Pd-catalyzed carbonylation reaction of iodoarenes and thiols to form thioesters. Recycling of the ionic liquid containing active Pd-catalyst was also demonstrated.
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