Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 13, Pages 5163-5166Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo800797c
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Gold(I)-catalyzed cycloisomerization of 1,7- and 1,8-enyne propargylic acetates afforded cyclopropyl derivatives containing seven- and eight-membered rings, respectively. This reaction was used for the synthesis of a new allocolchicinoid having a cyclopropane ring fused to the B seven-membered ring at the C6-C7 positions.
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