Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 21, Pages 8623-8626Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801469x
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- European Social Fund
- National Resources (EPEAEK II)
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The addition of (pentafluoroethyl)- and (heptafluoropropyl)lithium to Various acyl derivatives was studied. Weinreb and morpholine amides led to polyfluoro ketones in high to quantitative yields in short reaction times. Derivatives of 2-fluorocarboxylic acids may produce 1,1,1,2,2,4-hexafluoro ketones and 1,1,1.2,2,3,3,5-octafluoro ketones. The methodology can provide inhibitors for various lipolytic enzymes, including phospholipase A,,
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