Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 21, Pages 8422-8436Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo8015852
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Funding
- Fonds der Chernischen Industrie
- SFB 749
- DFG
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A wide range of polyfunctional aryl, heteroaryl, alkyl, and benzylic zinc reagents were coupled with unsaturated aryl halides bearing an acidic NH or OH proton, using Pd(OAc)(2) (1 mol %) and S-Phos (2 mol %) as catalyst without the need of protecting groups. A similar nickel-catalyzed reaction is described. The relative kinetic basicity of orcyanozinc compounds as well as their stability toward acidic protons is also described.
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