Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 18, Pages 7436-7439Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801365z
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Funding
- University of Ottawa
- NSERC
- Merck Frosst Canada
- Merck and Co.
- Boehringer Ingelheim
- PREA
- Le Fonds Quebecois de la Recherche sur la Nature et les Technologies (FQRNT)
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An efficient enantioselective synthesis of (+)-isofregenedol was achieved in 13 steps from commercially available cyclohexene oxide without the use of protecting groups. The tetrahydronaphthalenic core of isofregenedol was obtained via a gold(I)-catalyzed benzannulation recently developed in our laboratory.
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