Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 18, Pages 7383-7386Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801093n
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Funding
- CNRS
- interregional CRUNCH network
- INSA
- University of Rouen
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A straightforward route toward 2-(hetero)arylated and 2,5-di(hetero)arylated oxazoles through regiocontrolled palladium-catalyzed direct (hetero)arylation of ethyl oxazole-4-carboxylate with iodo-, bromo-, and chloro(hetero)aromatics followed by a two-step hydrolysis/decarboxylation sequence was described. The method was applied here to a neat synthesis of two 2.5-di(hetero)aryloxazole natural products, balsoxin and texaline.
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