Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 8, Pages 3197-3204Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo800069k
Keywords
-
Categories
Ask authors/readers for more resources
The alpha-lithiation-trapping sequence of trans-N-alkyl-2,3-diphenylaziridines (s-BuLi or s-BuLi/TMEDA), taking place with a stereochemistry which dramatically depends on the solvent coordinating ability (inversion of configuration in THF and retention in toluene), has been carefully investigated. H-1,C-13, and Li-7 multinuclear NMR investigations at low temperature suggest that two differently configured lithiated aziridines (monomeric cis-1-Li in THF and dimeric trans-1-Li in toluene) are involved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available