Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 1, Pages 298-300Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo7022087
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[GRAPHICS] The rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes effectively proceeds in a 1:2 manner via cleavage of C-H and C-C bonds to produce the corresponding naphthalene derivatives. Addition of trior tetraphenylcyclopentadiene as a ligand is crucial for the reaction to occur efficiently.
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