Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 22, Pages 9061-9064Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801942h
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Funding
- Basic Research of China [2006BAI01B02]
- National Natural Science Foundation of China [20721003, 20872153]
- 863 Hi-Tech Program of China [2006AA020602]
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We developed a highly efficient and practical protocol for the coupling of terminal alkynes with aryl iodides that is catalyzed by inexpensive and environmentally benign Fe/Cu. A broad spectrum of substrates can participate in the process effectively to produce desired products in good yields. The versatility, generality, low cost, and environmental friendliness, in combination with exceptionally high reaction rates, render this method particularly attractive for industrial applications.
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