Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 17, Pages 6686-6690Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo800930g
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- MIUR (Rome)
- CNR (Italy)
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Polyfunctionalized benzo[d]sultams 7 and 8, which contain an alpha-amino acid unit, have been synthesized from the corresponding open chain (pentafluorobenzene)sulfonamides 4 by complementary solid-liquid phase transfer catalysis (SL-PTC) and homogeneous protocols. The cyclization step proceeds through the intramolecular nucleophilic displacement of an aromatic fluorine atom.
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