Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 16, Pages 6425-6428Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo800866w
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A new LiI-promoted O- to N-alkyl migration has been developed for the conversion of O-alkylated 2-hydroxy pyridines, quinolines, and pyrimidines to the corresponding N-alkylated heterocycles in good to excellent yields (57-99%). This method serves as an efficient means for the preparation of N-benzyl pyridones, quinolones, and pyrimidones.
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