4.6 Article

Competition between electron transfer, trapping, and recombination in CdS nanorod-hydrogenase complexes

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 17, Issue 8, Pages 5538-5542

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp05993j

Keywords

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Funding

  1. NSF CAREER Award [CHE-1151151]
  2. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC0010334]
  3. U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences
  4. U.S. Department of Energy [DE-AC36-08-GO28308]
  5. National Renewable Energy Laboratory for CaI purification, and biochemical studies
  6. Direct For Mathematical & Physical Scien
  7. Division Of Chemistry [1151151] Funding Source: National Science Foundation
  8. U.S. Department of Energy (DOE) [DE-SC0010334] Funding Source: U.S. Department of Energy (DOE)

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Electron transfer from photoexcited CdS nanorods to [FeFe]-hydrogenase is a critical step in photochemical H-2 production by CdS-hydrogenase complexes. By accounting for the distributions in the numbers of electron traps and enzymes adsorbed, we determine rate constants and quantum efficiencies for electron transfer from transient absorption measurements.

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