Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 17, Issue 4, Pages 2335-2338Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp04685d
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Funding
- EPSRC [EP/H040218/1]
- EPSRC [EP/M023532/1, EP/H040218/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H040218/1, EP/M023532/1] Funding Source: researchfish
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Two diacetylide-triphenylamine hole-transport materials (HTM) with varying redox potential have been applied in planar junction TiO2-[CH3NH3] PbI3-xClx solar cells leading to high power-conversion efficiencies up to 8.8%. More positive oxidation potential of the HTM gives higher V-OC and lower J(SC) illustrating the role of matching energy levels, however both HTMs gave efficient cells despite a difference of 0.44 V in their redox potentials.
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