4.6 Article

Intriguing emission properties of triphenylamine-carborane systems

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 17, Issue 24, Pages 15679-15682

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp01658d

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Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2014R1A6A1030732]
  2. Industrial Core Technology Development Program - Ministry of Trade, Industry & Energy (MI, Korea) [10044876]

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Electron donor-acceptor (D-A) systems with a triphenylamino moiety (D) and ortho-carborane (A) show three kinds of intriguing emissions that can be attributed to the local excited state, the intramolecular charge-transfer state, and the aggregation-induced emission state. The emission behaviors depend on which positions of the carborane are substituted.

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