Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 17, Issue 3, Pages 1562-1566Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp04871g
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Funding
- EPSRC [EP/K006851/1]
- ERC
- EPSRC [EP/K039946/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039946/1, EP/K006851/1] Funding Source: researchfish
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The immobilisation of electrocatalysts for CO2 reduction onto light harvesting semiconductors is proposed to be an important step towards developing more efficient CO2 reduction photoelectrodes. Here, we report a low cost nickel cyclam complex covalently anchored to a metal oxide surface. Using transient spectroscopy we validate the role of surface immobilisation on enhancing the rate of photoelectron transfer. Furthermore [Ni(1,4,8,11-tetraazacyclotetradecane-6-carboxylic acid)](2+) (2) is shown to be a very active electrocatalyst in solution.
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