Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 17, Issue 12, Pages 8053-8060Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp05826g
Keywords
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Funding
- Fundamental Research Funds for the National Natural Science Foundation of China [51272022]
- National High Technology Research and Development Program of China (863 Program) [2013AA032205]
- Research Fund for the Doctoral Program of Higher Education [20120009130005, 20130009130001]
- Fundamental Research Funds for the Central Universities [2012JBZ001]
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Organic photovoltaics (OPVs) were fabricated with blended active layers of poly[[4,8-bis[(2-ethylhexyl)-oxy]benzo[1,2-b: 4,5-b'] dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophene-diyl]]:[6,6]-phenylC71-butyric acid methyl ester (PTB7:PC71BM). The active layers were prepared in chlorobenzene (CB) with different additives of 1,8-diiodooctane (DIO) and 1,8-dibromooctane and different concentrations using a wet process with spin coating. The effects of different solvent additives were studied with respect to photovoltaic parameters such as fill factor, short circuit current density, and power conversion efficiency. The absorption and surface morphology of the active layers were investigated by UV-visible spectroscopy, atomic force microscopy (AFM) and time-of-flight secondary ion mass spectrometry (TOF-SIMS), respectively. The results indicated that structural and morphological changes were induced by the solvent additives. The polymer solar cells (PSCs) of PTB7/PC71BM prepared by a spin coating method using DIO and 1,8-dibromooctane showed more improved PCE of 6.76%. The enhancement of performance of PSCs could be mainly attributed to the absorption enhancement and the improved charge carrier transportation.
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