Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 17, Issue 45, Pages 30255-30259Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp05168a
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Funding
- Core Research for Evolutional Science and Technology (CREST) of Japan Science and Technology (JST) Agency
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An extraordinary high-speed synthesis of gold nanoparticles (AuNPs) was discovered by synthesizing the AuNPs in ethanol-water mixtures using a solution plasma process (SPP). The influence of the ethanol mole fraction (vethanol) in the ethanol-water mixtures on the reduction rate of gold chloride ions to AuNPs under the SPP system was studied. The results indicated that the reaction rate of the AuNPs synthesis exhibited a maximum value (i.e. 35.2 times faster than in a pure water system) at the significant point where the partial molar volumes of ethanol and water changed drastically.
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