Application of a boron doped diamond (BDD) electrode as an anode for the electrolytic reduction of UO2 in Li2O-LiCl-Kcl molten salt

A boron doped diamond thin film electrode was employed as an inert anode to replace a platinum electrode in a conventional electrolytic reduction process for UO2 reduction in Li2O-LiCl molten salt at 650 degrees C. The molten salt was changed into Li2O-LiCl-KCl to decrease the operation temperature to 550 degrees C at which the boron doped diamond was chemically stable. The potential for oxygen evolution on the boron doped diamond electrode was determined to be approximately 2.2 V vs. a Li-Pb reference electrode whereas that for Li deposition was around -0.58 V. The density of the anodic current was low compared to that of the cathodic current. Thus the potential of the cathode might not reach the potential for Li deposition if the surface area of the cathode is too wide compared to that of the anode. Therefore, the ratio of the surface areas of the cathode and anode should be precisely controlled. Because the reduction of UO2 is dependent on the reaction with Li, the deposition of Li is a prerequisite in the reduction process. In a consecutive reduction run, it was proved that the boron doped diamond could be employed as an inert anode. (c) 2012 Elsevier B.V. All rights reserved.