Optical absorption and structural studies of bismuth borate glasses containing Er3+ ions

Glasses with composition xBi(2)O(3)-24Na(2)O-(75 - x)B2O3-1Er(2)O(3) (where x = 0, 5, 10, 15, 25, 33, 40 mol%), were prepared by the melt quenching technique. The effect of Bi2O3 content on thermal stability, optical properties and structures of these glasses is systematically investigated by X-ray diffraction, infrared spectroscopy and DTA techniques. The variations in the optical band gap energies, with Bi2O3 content have been discussed in terms of changes in the glass structure. Urbach energy increases with increasing Bi2O3 content in the present glass system. It is found that the density, molar volume and optical basicity increase with increasing Bi2O3. The glass transition temperature (T-g) of the samples was found to decrease with the Bi2O3 content. IR measurements revealed an existence of trigonal BO3 pyramid, tetrahedron BO4, pyramidal BiO3 and octahedron BiO6 structural units in the network of the investigated glass. Furthermore, a decrease in BO4 and an increase in BO3 take place against the increase of x which means that, Bi2O3 plays the role of network modifier in the structural network. (c) 2013 Elsevier B.V. All rights reserved.