4.5 Article

Theoretical stability, thin film synthesis and transport properties of the Mon+1GaCn MAX phase

Journal

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
Volume 9, Issue 3, Pages 197-201

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssr.201409543

Keywords

superconducting MAX phases; Mo2GaC; ab-initio calculations; magnetron sputtering; thin films

Funding

  1. European Research Council under European Community/ERC [258509]
  2. Swedish Research Council (VR) [642-2013-8020, 621-2012-4425]
  3. KAW Fellowship program
  4. SSF synergy grant FUNCASE
  5. Icelandic Research Fund

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The phase stability of Mon +1GaCn has been investigated using ab-initio calculations. The results indicate stability for the Mo2GaC phase only, with a formation enthalpy of 0.4 meV per atom. Subsequent thin film synthesis of Mo2GaC was performed through magnetron sputtering from elemental targets onto Al2O3 [0001], 6H-SiC [0001] and MgO [111] substrates within the temperature range of 500 degrees C and 750 degrees C. High structural quality films were obtained for synthesis on MgO [111] substrates at 590 degrees C. Evaluation of transport properties showed a superconducting behavior with a critical temperature of approximately 7 K, reducing upon the application of an external magnetic field. The results point towards the first superconducting MAX phase in thin film form. (C) 2015 WILEY-VCH Verlag GmbH &Co. KGaA, Weinheim)

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