Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 190, Issue 7, Pages 1138-1145Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2014.978321
Keywords
Thiocyanation; indole; AlCl3; solvent-free conditions
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Aluminum chloride/Ammonium thiocyanate (AlCl3/NH4SCN) was found to be an effective system for the thiocyanation of some arylamines and indoles to afford the corresponding thiocyanated adducts at room temperature under solvent-free conditions. The efficacy of this combined reagent was also examined in the thiocyanation of pyrrole and isatin. A plausible mechanism of thiocyanation has also been suggested.
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