Journal
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES
Volume 373, Issue 2037, Pages -Publisher
ROYAL SOC
DOI: 10.1098/rsta.2014.0187
Keywords
solid state; organometallic; reactivity; catalysis
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Funding
- EPSRC [EP/L505031/1]
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Acting as a bridge between the heterogeneous and homogeneous realms, the use of discrete, well-defined, solid-state organometallic complexes for synthesis and catalysis is a remarkably undeveloped field. Here, we present a review of this topic, focusing on describing the key transformations that can be observed at a transition-metal centre, as well as the use of well-defined organometallic complexes in the solid state as catalysts. There is a particular focus upon gas-solid reactivity/catalysis and single-crystal-to-single-crystal transformations.
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