Journal
JOURNAL OF NATURAL PRODUCTS
Volume 77, Issue 7, Pages 1718-1723Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np500458a
Keywords
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Funding
- National Natural Science Fundation of China [41176120, 21372208]
- NSFC-Shandong Joint Fund [U1406402]
- National High Technology Research and Development Program of China [2013AA092901]
- Program for New Century Excellent Talents in University [NCET-12-0499]
- Public Projects of State Oceanic Administration [2010418022-3]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0944]
- Hungarian National Research Foundation [OTKA K105871]
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Eleganketal A (1), a naturally occurring aromatic polyketide possessing a rare highly oxygenated spiro[isobenzofuran-1,3'-isochroman] ring system, was isolated from the fungus Spicaria elegans KLA03 by culturing it in a modified mannitol-based medium. The structure of 1 including the absolute configuration was determined by combining spectroscopic analysis, synthesis of the racemic permethylated analogue, chiral-phase HPLC separation, and TDDFT-ECD analysis.
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