Journal
JOURNAL OF NATURAL PRODUCTS
Volume 77, Issue 6, Pages 1541-1544Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np5003065
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Funding
- Naito Foundation
- Grants-in-Aid for Scientific Research [25460115, 25670043] Funding Source: KAKEN
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The absolute configurations at six stereogenic centers in amphidinin A (1), a cytotoxic linear polyketide isolated from a symbiotic marine dinoflagellate, Amphidinium sp., were elucidated to be 2R, 4R, 6S, 9R 11R, and 12S by the combination of J-based configuration analysis, modified Mosher's method, and density-functional theory calculations.
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