Journal
JOURNAL OF NATURAL PRODUCTS
Volume 75, Issue 4, Pages 644-649Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np200886x
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Funding
- ICBG from Fogarty (NIH) [U01TW008163]
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Two new compounds, the peptide polyketide glycoside totopotensamide A (1) and its aglycone totopotensamide B (2), were isolated from a Streptomyces sp. cultivated from the gastropod mollusk Lienardia totopotens collected in the Philippines. The compounds contain a previously undescribed polyketide component, a novel 2,3-diaminobutyric acid-containing macrolactam, and a new amino acid, 4-chloro-5,7-dihydroxy-6-methylphenylglycine. The application of Marfey's method to phenylglycine derivatives was explored using quantum mechanical calculations and NMR.
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