Journal
JOURNAL OF NATURAL PRODUCTS
Volume 73, Issue 11, Pages 1846-1852Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np1004888
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Treatment of the crude ether-insoluble resin glycoside (convolvulin) from seeds of Pharbitis nil (Pharbitis Semen), called pharbitin, with indium(III) chloride in methanol provided seven oligoglycosides of hydroxy fatty acid methyl esters partially acylated by 2-methyl-3-hydroxybutyric (nilic) and 2S-methylbutyric acids. Their structures were elucidated on the basis of NMR and MS data and chemical conversions.
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