Journal
JOURNAL OF NATURAL PRODUCTS
Volume 73, Issue 6, Pages 1049-1052Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np900765y
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Funding
- Indena Spa
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The fermentation of 10-deacetylbaccatine III (10-DAB) (1) with Curvularin lunata afforded 4-deacylwallifoliol (4) and wallifoliol (5), the only natural taxoid with the unusual 5/6/6/6/4 ring system. The X-ray structure of compound 4 is reported. The skeletal rearrangements induced by the microbial enzymatic systems are also discussed.
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