Journal
JOURNAL OF NATURAL PRODUCTS
Volume 71, Issue 11, Pages 1946-1948Publisher
AMER CHEMICAL SOC
DOI: 10.1021/np800325z
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The isolation of aurachin P (2) from Stigmatella erecta strain Pd e32 is described. Spectroscopic data, in particular NMR data, indicate it is 1 '-hydroxyaurachin A with a 1 ' R,2 ' S,3 ' R relative configuration. In addition, a further compound, 5-nitroresorcinol (4a), was isolated and identified as a novel natural product. Feeding of C-13- and N-15-labeled precursors indicated this was synthesized solely from glucose and ammonia. To account for the labeling pattern, phloroglucinol (8) is postulated as an intermediate branching off from 3-dehydroquinate (7) in the shikimate pathway.
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