4.4 Article

Critical point of martensitic transformation under stress in an Fe-31.2Pd (at.%) shape memory alloy

Journal

PHILOSOPHICAL MAGAZINE
Volume 95, Issue 12, Pages 1390-1398

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/14786435.2015.1029561

Keywords

Fe-based alloys; structural transitions; thermal expansion; solid-state transformation; martensitic transformations; mechanical properties; phase diagrams; diffusionless transformations

Funding

  1. Japan Society for the Promotion of Science [23360280, 26289230]
  2. Grants-in-Aid for Scientific Research [23360280, 26289230] Funding Source: KAKEN

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We have examined the transformation strain, Delta epsilon, in the [001] direction of an Fe-31.2Pd (at.%) shape memory alloy under compressive stress applied in the same direction. When the stress is absent, the alloy exhibits a cubic to tetragonal martensitic transformation at 230K with |Delta epsilon| of 1.4%. As the stress increases, the transformation temperature increases linearly and |Delta epsilon| decreases linearly and vanishes at 40MPa (280K). This point is the critical point of this transformation at which the first-order nature disappears, and the critical exponent beta is evaluated to be 0.47 +/- 0.04.

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