4.2 Article

Two-Photon Excitation Behavior of Thiophene-Based Oligomers and a Polymer

Journal

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume 9, Issue 1, Pages 670-672

Publisher

AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2009.J070

Keywords

alpha-Conjugated Polymer; Oligomer; Two-Photone Excitation

Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology, Japan

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The two-photon excitation action cross-sections of four kinds of co-oligomers of thiophene and pyridine (e.g., Py-(Th)(n)-Py; Py = 2-pyridyl, Th = thiophene-2,5-diyl; n = 3, 4) and a copolymer constituted of alternating pyridazine and 4,4'-dihexyl- 2,2'-bithiophene units have been measured by using a reported value ((sigma(2PE) at 780 nm = 10 GM) of green fluorescent protein as the reference. The co-oligomers give sigma(2PE) values of 14-26 GM and the copolymer shows sigma(2PE) of 23 GM.

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