Journal
JOURNAL OF NANOPARTICLE RESEARCH
Volume 16, Issue 5, Pages -Publisher
SPRINGER
DOI: 10.1007/s11051-014-2395-1
Keywords
Hydrothermal synthesis; Spinel ferrites; Core/shell nanoparticles; Magnetic properties
Categories
Funding
- Engineering and Physical Science research Council
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Core/shell hetero-nanostructures of hydrothermally synthesised cobalt and nickel ferrites are shown to exhibit novel magnetic properties. The compositions and phase distributions of homogeneous Co0.5Ni0.5Fe2O4, and core/shell NiFe2O4-Core/CoFe2O4-Shell and CoFe2O4-Core/NiFe2O4-Shell nanoparticles (NPs) are confirmed using high-resolution transmission electron microscopy and electron energy loss spectroscopy. SQUID magnetometry investigations demonstrate that, at room temperature, homogeneous Co0.5Ni0.5Fe2O4 NPs (similar to 8 nm in diameter) are in the super-paramagnetic state, the magnetisation of NiFe2O4-Core/CoFe2O4-Shell NPs (similar to 11 nm in diameter) is partially blocked, whilst CoFe2O4-Core/NiFe2O4-Shell NPs (similar to 11 nm in diameter) are in a blocked state. In particular, NiFe2O4-Core/CoFe2O4-Shell NPs exhibit twice the out-of-phase chi '' susceptibility of CoFe2O4-Core/NiFe2O4-Shell NPs, being dominated by the magnetisation of the core ferrite phase. Hence, when exposed to a high-frequency magnetic field, it is considered that the high chi '' susceptibility of NiFe2O4-Core/CoFe2O4-Shell NPs will promote large magnetically induced heating effects, making these core/shell NPs strong candidates for hyperthermia applications.
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