Journal
JOURNAL OF NANOPARTICLE RESEARCH
Volume 14, Issue 4, Pages -Publisher
SPRINGER
DOI: 10.1007/s11051-012-0804-x
Keywords
Core-shell nanowires; Vertically aligned nanowires; Photoanode material; ZnO; ZnGa2O4
Categories
Funding
- JSPS
- Global COE
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [22360056]
- Grants-in-Aid for Scientific Research [11J04501, 22360056] Funding Source: KAKEN
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Dense and vertically aligned ZnO-ZnGa2O4 core-shell nanowires were synthesized in large scale on a-plane sapphire substrates by a simple two-step chemical vapor deposition method. The synthesized ZnO-ZnGa2O4 core-shell nanowires were connected through their base by a thick underlayer of the same material realizing electrical contact of the nanostructured array. X-ray diffraction and transmission electron microscopy analyses of the core-shell nanowires reveal that the ZnO cores and ZnGa2O4 shells of the core-shell nanowires are of single-crystal quality and have aligned crystallographic orientations. The ultraviolet-visible diffuse reflectance spectra of the core-shell nanowires showed two sharp edges corresponding to near-band-edge absorption contributed by the ZnO cores and the ZnGa2O4 shells. Moreover, the room-temperature photoluminescence spectra of the core-shell nanowires gave three UV emission peaks coming from the ZnGa2O4 shells and the ZnO cores. The dense and vertically aligned ZnO-ZnGa2O4 core-shell nanowires showing promising photoelectric properties offer an ideal structure for light harvesting applications such as a photoanode in a photoelectrochemical water splitting cell.
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