Formation of AgFeO2, α-FeOOH, and Ag2O from mixed Fe(NO3)3-AgNO3 solutions at high pH

Precipitation of ternary oxide silver ferrite (AgFeO2), iron oxyhydroxide goethite (alpha-FeOOH) and silver(I) oxide (Ag2O) from mixed Fe(NO3)(3)-AgNO3 solutions in a whole [Ag+]:[Fe3+] concentration ratio range at high pH was investigated using X-ray powder diffraction (XRD), Fe-57 Mossbauer, FT-IR and UV-Vis-NIR spectroscopies and field emission scanning electron microscopy (FE-SEM). Strong alkalis organic tetramethylammonium hydroxide (TMAH) or inorganic NaOH were used as precipitating agents. Monodispersed lath-like alpha-FeOOH particles were formed from a pure Fe(NO3)(3) solution. The presence of Ag+ ions influenced the formation of the delafossite-type ternary oxide AgFeO2 beside alpha-FeOOH. The positions of XRD and Mossbauer lines did not suggest any significant incorporation of Ag+ ions into the alpha-FeOOH structure. AgFeO2 was formed in the precipitation system with the equimolar initial [Ag+]:[Fe3+] concentration ratio. The size and shape of AgFeO2 particles, as well as their structural polytype (2H or 3R), were dependent on reaction temperature, aging time and alkali used. In systems with an excess of Ag+ ions mixtures of AgFeO2 and Ag2O were formed. Single phase Ag2O precipitated from a pure AgNO3 solution. (c) 2012 Elsevier B.V. All rights reserved.