4.7 Article

Simultaneous application of ultrasonic irradiation and immobilized ionic liquid onto the SBA-15 nanoreactor (US/[MPIm]Cl@SBA-15): A robust, recyclable, and useful combined catalytic system for selective and waste-free Kabachnik Fields reaction

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 195, Issue -, Pages 30-34

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2014.01.031

Keywords

Immobilization; Ionic liquid; Ultrasound; Phosphonate; Kabachnik-Fields reaction; Multicomponent reaction

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Simultaneous application of the ultrasonic irradiation (US) and immobilized ionic liquid (IL@SBA-15) is used as an alternative to conventional catalysts in the Kabachnik-Fields reaction of an amine, aldehyde with phosphite leading to the formation of (alpha-aminoalkyl)phosphonate. The reaction time is reduced drastically and the reaction is progressed in an environmentally friendly way. The yields are around 93-96%. (C) 2014 Elsevier B.V. All rights reserved.

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