Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 376, Issue -, Pages 7-12Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2013.04.006
Keywords
Functionalized palladium nanoparticles; Suzuki reaction; Cyclohexadiene hydrogenation; Styrene hydrovinylation; Sequential reactions
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Funding
- MICINN [CTQ2009-08795, CTQ2010-15292]
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Palladium nanoparticles peripherally functionalized with RuCl2(p-cymene) (NP2), RhCl(cod) (NP3) and PdCl(eta(3)-2-MeC3H4) (NP4) units show catalytic activity in C-C coupling reactions, hydrogenation and hydrovinylation processes. We report for the first time an example of a catalytic precursor for the hydrovinylation/C-C coupling sequential process by using the two catalytic centres displayed by NP4, the Pd core and the PdCl(eta(3)-2-MeC3H4) moieties. (C) 2013 Elsevier B.V. All rights reserved.
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