Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 360, Issue -, Pages 61-70Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2012.04.010
Keywords
Bronsted acidic ionic liquids; Hydration reaction; Acid catalyst; Hammett acidity; Acid value; DFT calculations
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Funding
- Department of Science and Technology, New Delhi (DST) [SR/S1/PC/31/2009]
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In this study, a variety of imidazole based sulfonic acid group functionalized Bronsted acidic ionic liquids (BAILs) were synthesized. BAILs have been successfully developed as task specific ionic liquids for hydration of alkynes under mild conditions to give high yields of ketones as a selective product. Acidity of BAILs was determined using volumetric titration and UV-visible spectroscopic methods. The Hammett acidity order and acid value of BAILS correlate well with the activity order observed for most of the BAILs in the hydration reaction of phenylacetylene. Theoretical studies demonstrate that hydrogen bonding plays a key role in tuning the acidity of BAILs. Density function theory calculations are also able to explain the difference in activity observed in these BAILS. The activity of ionic liquids was theoretically studied by computing the activation energy for the hydration reaction. Recycling experiments suggest that these novel BAILS can be reused without significant loss in activity. BAILS are simple and easy to prepare and exhibit excellent activity toward the hydration of a variety of alkynes to ketones. Moreover, the reaction involving BAILS does not involve heavy metal catalysts or H2SO4. Novel BAILs offer several attractive features such as sustainable synthetic route, low cost, moisture stability, high yields, and recyclability. (c) 2012 Elsevier B.V. All rights reserved.
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