Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 349, Issue 1-2, Pages 86-93Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2011.08.024
Keywords
Ring opening polymerization; Cu(OAc)(2); Lactide; Coordination-insertion mechanism; Activated monomer mechanism
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Funding
- Council of Scientific and Industrial Research, New Delhi
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Cu(OAc)(2) was assessed to be a good catalyst for the bulk ring opening polymerization of lactides. These polymerizations are highly controlled leading to the formation of polymer with expected number average molecular weights and narrow molecular weight distribution. This method may be used to synthesize polymers with different end terminal groups. The over all process is green, since these polymers being biodegradable and the system is independent of solvents. (C) 2011 Elsevier B.V. All rights reserved.
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