Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 334, Issue 1-2, Pages 13-19Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2010.10.015
Keywords
Carbapalladacycle; MMT-clay; Organic-inorganic hybrid materials; Mizoroki-Heck; Sonogashira
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Funding
- IFCPAR, New Delhi [3405-2]
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An efficient synthesis of an ammonium tagged carbapalladacycle 5, in modest yield, has been achieved. Further, the clay-nanocomposite 6 was prepared by ion exchange of 5 into clay interlayers as a new organic-inorganic hybrid catalytic system. The ionic tag of the ammonium supported carbapalladacycle 5 assists in the pillaring process and enhances the organophilicity of catalyst 6 in the interlayers of clay. The catalytic activity in ammonium based ionic liquid (TMBA] NTf2 of both the homogeneous and heterogeneous recyclable catalysts 5 and 6 respectively in micromolar concentration of palladium has been tested for Mizoroki-Heck and Sonogashira reactions in good yields with high TON/TOF and negligible metal leaching. Effect of solvent and temperature on the catalytic activity has also been examined. (C) 2010 Elsevier B.V. All rights reserved.
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