Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 323, Issue 1-2, Pages 40-44Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2010.03.007
Keywords
A(3)-coupling reaction; Glycol; Heterogeneous catalysis; SBA-15; Silver nanoparticles
Categories
Funding
- National Nature Science Foundation of China [20872135]
- China National Tobacco Corporation [110200701007]
Ask authors/readers for more resources
The mesoporous SBA-15 supported silver nanoparticles catalyst system with a highly ordered hexagonal mesostructure was prepared by an in situ reduction method using hexamethylenetetramine as mild and efficient reducing agent. These AgSBA-15 materials act as environmentally friendly catalysts in A(3)-coupling reactions of aldehydes, amines, and terminal alkynes with glycol as a green solvent. It is also found that the maximum reaction yield has been obtained for an average Ag-nanoparticle size of about 8 nm. The catalyst could also be recovered easily and used repetitively four times without significantly affecting the catalytic activity. The heterogeneous catalysts were fully characterized by N-2 adsorption and desorption, XRD, TEM, ICP and XPS. (C) 2010 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available