Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 281, Issue 1-2, Pages 200-206Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2007.11.008
Keywords
ZrO2-TiO2 mixed oxides; acidic properties; mixed Zr-O-Ti bond; structural and morphological characterization; NOx adsorption
Categories
Ask authors/readers for more resources
Single ZrO2, TiO2 and mixed ZrO2-TiO2 oxides with various Zr:Ti ratio (90:10, 50:50 and 10:90) were prepared by the sol-gel method. The samples were characterized by DSC, nitrogen adsorption, SEM, XRD, molecular simulation and DRIFE According to the ZrO2/TiO2 ratio, the experimental results reveal that the TiO2 loading into ZrO2 had effects on shifts of exothermic peaks towards higher temperature, attributed to transition from amorphous to crystalline phase except in the ZT50 xerogel. The optimum concentration of titania into mixed ZrO2-TiO2 oxides to obtain high surface area (similar to 230 m(2)/g) and highly acidic surface was in the equimolar composition. An amorphous XRD pattern was observed in the ZT50 sample, this behaviour was related to the mixed Zr-O-Ti bond formed, which caused an atomic disorder in the structure of the sample and this result was confirmed by molecular simulation. All the oxides were constituted by microspheroid particles regardless of the Zr/Ti molar ratio and crystalline phase. Different kinds of surface nitrates (NOx, x = 2, 3) species were observed on the mixed ZrO2-TiO2 samples; these species are formed on Lewis sites and the amount of these species on the surface oxide is intimately related to the support acidity, which in turn depends on the specific area of the samples, as well as, on the Zr/Ti ratio and the Zr-O-Ti bond population. Bridged and bidentate NO3- species are adsorbed on the Zr-rich samples. (c) 2007 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available